The Classes of Molybdenum-Base Alloys
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- Category: Molybdenum knowledge
- Published on 16 September 2013
- Written by 陈桂兰
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Four main classes of commercial molybdenum-base alloys exist. The most common of the carbide-strengthened alloys is known as TZM, containing about 0.5% titanium, 0.08% zirconium, and 0.03% carbon. Other alloys in this class include TZC (1.2% titanium, 0.3% zirconium, 0.1% carbon), MHC (1.2% hafnium, 0.05% carbon), and ZHM (1.2% hafnium, 0.4% zirconium, 0.12% carbon). The high-temperature strength imparted by these alloys is their main reason for existence. Both TZM and MHC have found application as metalworking tool materials. Their high-temperature strength and high thermal conductivity make them quite resistant to the collapse and thermal cracking that are common failure mechanisms for tooling materials.
Tungsten and rhenium are the two primary solid-solution alloys. The most common compositions are 30% tungsten (Mo-30W), 5% rhenium (Mo-5Re), 41% rhenium (Mo-41Re), and 47.5% rhenium (Mo-50Re). With the exception of the Mo-30W alloy which is available as a vacuum-arc-cast product, these alloys are normally produced by powder metallurgy. The tungsten-containing alloys find application as components in systems handling molten zinc, because of their resistance to this medium. They were developed as a lower-cost, lighter-weight alternative to pure tungsten and have served these applications well over the years. The 5% rhenium alloy is used primarily as thermocouple wire, while the 41% and 47.5% alloys are used in structural aerospace applications.
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