Molybdenum Blue
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- Category: Molybdenum knowledge
- Published on 27 August 2013
- Written by 陈桂兰
- Hits: 809
Molybdenum blue is a term applied to:
reduced heteropolymolybdate complexes, polyoxometalates containing Mo(V), Mo(VI), and a hetero atom such as phosphorus or silicon
reduced isopolymolybdate complexes, polyoxometalates containing Mo(V), Mo(VI) formed when solutions of Mo(VI) are reduced
a blue pigment containing molybdenum(VI) oxide
The "heteropoly-molybdenum blues", are used extensively in analytical chemistry and as catalysts. The formation of "isopoly-molybdenum blues" which are intense blue has been used as a sensitive test for reducing reagents. They have recently been shown to contain very large anionic species based on the so-called "big wheel" containing 154 Mo atoms.
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